IRON EARTHS
Miscellaneous
- Family: None
- Region: None
- Mined At: Unspecified
- Raw Mineral: Yes
- Generic: No
Notes
(Richard Willis)
Iron is the third most abundant element in earths first, aluminum (Al); second, silicon (Si). Just as clay contains Al and Si virtually by definition, virtually any clay contains iron (Fe) by fiat. see spinel
Ferric oxide earths, such as the ochres, with significant percentages of manganese and other metals make them suitable as engobes to smoke-scorch before glazing in order to blacken the clay body and to effect a metallic sheen. Primitive pottery was so colored and often then burnished, frequently with a graphite to increase the polished sheen. With the advent of glazes the iron-colored body was usually covered with a transparent glaze to effect the polish. Examples are the celadons of Chi
na, the red-glost pottery of Rome, and the aka or red (black body, red glaze), raku wares of Korea and Japan. see Crocus Martis, limonite, ochre, etc.
popular iron-rich earths used in ceramics:
yellow ochre: hydrated ferric oxide (Fe2O3) [see, also, the titled entry yellow ochre]
red ochre: anhydrated ferric oxide
black, or shadow, ochre: hydrated FeO plus Mn
typical analyses of popular iron-rich minerals
goethite SiO2 5.4, Al2O3 4.3, Fe2O3 40.5, FeO 8.7, MnO 0.4, MgO 1.6, CaO 15.1, H2O 7.2, TiO2 0.2, P2O3 1.7, CO2 15.0, S 0.04
hematite SiO2 9.9, Al2O3 3.2, Fe2O3 67.8, FeO 10.0, MgO 0.4, CaO 2.4, H2O 2.8, TiO2 0.4, P2O3 2.3, CO2 1.1
chamosite SiO2 13.4, Al2O3 7.4, Fe2O3 8.5, FeO 31.9, MgO 2.5, CaO 6.1, H2O 8.5, P2O3 2.8, CO2 17.4, S 0.5
siderite SiO2 7.8, Al2O3 8.4, Fe2O3 1.7, FeO 35.6, MnO 0.4, MgO 4.0, CaO 10.5, H2O 4.2, TiO2 0.2, P2O3 1.3, CO2 25.3, S 0.1
Authors
- Richard Willis (Owner)
XML
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<material name="IRON EARTHS" descrip="" generic="0" rawmineral="1" searchkey="" loi="0.00">
<notes>
<note>Iron is the third most abundant element in earths &#151; first, aluminum (Al); second, silicon (Si). Just as &#147;clay&#148; contains Al and Si virtually by definition, virtually any clay contains iron (Fe) by fiat. <FONT SIZE=2>see <B><I>spinel</I></B></FONT><B><I><BR>
</I></B>Ferric oxide earths, such as the &#147;ochres&#148;, with significant percentages of manganese and other metals make them suitable as engobes to smoke-scorch before glazing in order to blacken the clay body and to effect a metallic sheen. Primitive pottery was so colored and often then burnished, frequently with a graphite to increase the polished sheen. With the advent of glazes the iron-colored body was usually covered with a transparent glaze to effect the polish. Examples are the celadons of Chi
na, the red-glost pottery of Rome, and the <B><I>aka</I></B> or &#147;red&#148; (black body, red glaze), raku wares of Korea and Japan. <FONT SIZE=2>see <B><I>Crocus Martis</I></B>, <B><I>limonite</I></B>, <B><I>ochre</I></B>, etc.</FONT><BR>
<B>popular iron-rich earths used in ceramics:<BR>
</B>&#151; yellow ochre: hydrated ferric oxide (Fe<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT>) [<FONT SIZE=2>see, also, the titled entry <B><I>yellow ochre</I></B>]</FONT><BR>
&#151; red ochre: anhydrated ferric oxide<BR>
&#151; black, or &#147;shadow&#148;, ochre: hydrated FeO plus Mn<BR>
<B>typical analyses of popular iron-rich minerals<BR>
</B>goethite &#151; SiO<FONT SIZE=2><SUB>2</SUB></FONT> 5.4, Al<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT> 4.3, Fe<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT><SUB> </SUB>40.5, FeO 8.7, MnO 0.4, MgO 1.6, CaO 15.1, H<FONT SIZE=2><SUB>2</SUB></FONT>O 7.2, TiO<FONT SIZE=2><SUB>2</SUB></FONT> 0.2, P<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT> 1.7, CO<FONT SIZE=2><SUB>2</SUB></FONT> 15.0, S 0.04<BR>
hematite &#151; SiO<FONT SIZE=2><SUB>2</SUB></FONT> 9.9, Al<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT> 3.2, Fe<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT><SUB> </SUB>67.8, FeO 10.0, MgO 0.4, CaO 2.4, H<FONT SIZE=2><SUB>2</SUB></FONT>O 2.8, TiO<FONT SIZE=2><SUB>2</SUB></FONT> 0.4, P<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT><SUB> </SUB>2.3, CO<FONT SIZE=2><SUB>2</SUB></FONT> 1.1<BR>
chamosite &#151; SiO<FONT SIZE=2><SUB>2</SUB></FONT> 13.4, Al<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT> 7.4, Fe<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT> 8.5, FeO 31.9, MgO 2.5, CaO 6.1, H<FONT SIZE=2><SUB>2</SUB></FONT>O 8.5, P<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT><SUB> </SUB>2.8, CO<FONT SIZE=2><SUB>2</SUB></FONT> 17.4, S 0.5<BR>
siderite&#151; SiO<FONT SIZE=2><SUB>2</SUB></FONT> 7.8, Al<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT> 8.4, Fe<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT><SUB> </SUB>1.7, FeO 35.6, MnO 0.4, MgO 4.0, CaO 10.5, H<FONT SIZE=2><SUB>2</SUB></FONT>O 4.2, TiO<FONT SIZE=2><SUB>2</SUB></FONT> 0.2, P<FONT SIZE=2><SUB>2</SUB></FONT>O<FONT SIZE=2><SUB>3</SUB></FONT> 1.3, CO<FONT SIZE=2><SUB>2</SUB></FONT> 25.3, S 0.1<BR>
</note>
</notes>
</material>
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