IRON

Miscellaneous

Notes

(Richard Willis)

Element, with the symbol Fe and atomic weight of 55.84
Ferric/ferrous oxide is the most refractory of the three oxides.
The iron oxides are probably the most widely used oxides to color clays and glazes throughout the history of ceramics. Certainly among prehistoric ceramics they were the most used colorants. In oxidizing firings reds, yellows and browns result; in reduction firings blacks, browns, and greys result — all else being equal. Clay and glaze colors, then, can tell the archaeologist, for instance, a great deal about the materials and techniques used in producing antique pottery. see colorants
water solubility & fusion ºC
— oxide (red) — soluble — 1565
— oxide (black) — nsoluble — 1480
commonly used forms
— ferrous oxide (black) FeO
— chromate Fe2O3, Cr2O3
— ferric oxide (red to yellow) Fe2O3
— sulfate FeSO4, 7H2O
— ferric/ferrous (red to yellow) Fe3O4
— ilmenite FeO, TiO2
— hydroxide Fe(OH)3
— picolite (Fe, Mg), (Al, Cr, Fe)2, O2
— chlorurium FeCl3
— franklinite (Zn, Mn), (Fe), (Mn), O4
— dichromate-ferric Fe2(Cr2O7)3

Authors

XML

<?xml version="1.0" encoding="UTF-8"?>
<material name="IRON" descrip="" generic="0" rawmineral="1" searchkey="" loi="0.00">
<notes>
<note>Element, with the symbol Fe and atomic weight of 55.84&lt;BR&gt;
Ferric/ferrous oxide is the most refractory of the three oxides.&lt;BR&gt;
The iron oxides are probably the most widely used oxides to color clays and glazes throughout the history of ceramics. Certainly among prehistoric ceramics they were the most used colorants. In oxidizing firings reds, yellows and browns result; in reduction firings blacks, browns, and greys result &amp;#151; all else being equal. Clay and glaze colors, then, can tell the archaeologist, for instance, a great deal about the materials and techniques used in producing antique pottery. see &lt;B&gt;&lt;I&gt;colorants&lt;BR&gt;
&lt;/I&gt;water solubility &amp;amp; fusion &amp;ordm;C&lt;BR&gt;
&lt;/B&gt;&amp;#151; oxide (red) &amp;#151; soluble &amp;#151; 1565&lt;BR&gt;
&amp;#151; oxide (black) &amp;#151; nsoluble &amp;#151; 1480&lt;BR&gt;
&lt;B&gt;commonly used forms&lt;BR&gt;
&lt;/B&gt;&amp;#151; ferrous oxide (black) FeO&lt;BR&gt;
&amp;#151; chromate Fe&lt;FONT SIZE=2&gt;&lt;SUB&gt;2&lt;/SUB&gt;&lt;/FONT&gt;O&lt;FONT SIZE=2&gt;&lt;SUB&gt;3&lt;/SUB&gt;&lt;/FONT&gt;, Cr&lt;FONT SIZE=2&gt;&lt;SUB&gt;2&lt;/SUB&gt;&lt;/FONT&gt;O&lt;FONT SIZE=2&gt;&lt;SUB&gt;3&lt;/SUB&gt;&lt;/FONT&gt;&lt;SUB&gt;&lt;BR&gt;
&lt;/SUB&gt;&amp;#151; ferric oxide (red to yellow) Fe&lt;FONT SIZE=2&gt;&lt;SUB&gt;2&lt;/SUB&gt;&lt;/FONT&gt;O&lt;FONT SIZE=2&gt;&lt;SUB&gt;3&lt;/SUB&gt;&lt;/FONT&gt;&lt;SUB&gt;&lt;BR&gt;
&lt;/SUB&gt;&amp;#151; sulfate FeSO&lt;FONT SIZE=2&gt;&lt;SUB&gt;4&lt;/SUB&gt;&lt;/FONT&gt;, 7H&lt;FONT SIZE=2&gt;&lt;SUB&gt;2&lt;/SUB&gt;&lt;/FONT&gt;O&lt;BR&gt;
&amp;#151; ferric/ferrous (red to yellow) Fe&lt;FONT SIZE=2&gt;&lt;SUB&gt;3&lt;/SUB&gt;&lt;/FONT&gt;O&lt;FONT SIZE=2&gt;&lt;SUB&gt;4&lt;/SUB&gt;&lt;/FONT&gt;&lt;SUB&gt;&lt;BR&gt;
&lt;/SUB&gt;&amp;#151; ilmenite FeO, TiO&lt;FONT SIZE=2&gt;&lt;SUB&gt;2&lt;/SUB&gt;&lt;/FONT&gt;&lt;SUB&gt;&lt;BR&gt;
&lt;/SUB&gt;&amp;#151; hydroxide Fe(OH)&lt;FONT SIZE=2&gt;&lt;SUB&gt;3&lt;/SUB&gt;&lt;/FONT&gt;&lt;SUB&gt;&lt;BR&gt;
&lt;/SUB&gt;&amp;#151; picolite (Fe, Mg), (Al, Cr, Fe)&lt;FONT SIZE=2&gt;&lt;SUB&gt;2&lt;/SUB&gt;&lt;/FONT&gt;, O&lt;FONT SIZE=2&gt;&lt;SUB&gt;2&lt;/SUB&gt;&lt;/FONT&gt;&lt;SUB&gt;&lt;BR&gt;
&lt;/SUB&gt;&amp;#151; chlorurium FeCl&lt;FONT SIZE=2&gt;&lt;SUB&gt;3&lt;/SUB&gt;&lt;/FONT&gt;&lt;SUB&gt;&lt;BR&gt;
&lt;/SUB&gt;&amp;#151; franklinite (Zn, Mn), (Fe), (Mn), O&lt;FONT SIZE=2&gt;&lt;SUB&gt;4&lt;/SUB&gt;&lt;/FONT&gt;&lt;BR&gt;
&amp;#151; dichromate-ferric Fe&lt;FONT SIZE=2&gt;&lt;SUB&gt;2&lt;/SUB&gt;&lt;/FONT&gt;(Cr&lt;FONT SIZE=2&gt;&lt;SUB&gt;2&lt;/SUB&gt;&lt;/FONT&gt;O&lt;FONT SIZE=2&gt;&lt;SUB&gt;7&lt;/SUB&gt;&lt;/FONT&gt;)&lt;FONT SIZE=2&gt;&lt;SUB&gt;3&lt;/SUB&gt;&lt;/FONT&gt;&lt;BR&gt;

</note>
</notes>
</material>



Much more information with complete interlinking to many related
databases can be found by logging into the www.ceramicmaterials.info database


Copyright 2003 http://digitalfire.com, All Rights Reserved
Please support http://ceramicmaterials.info to improve this library
instrial.gif (4460 bytes)

INSIGHT is ceramic chemistry
calculation software that runs on
Windows, Mac and Linux and talks
to this web site.